Tin dioxide sno 2 with tetragonal phase is an ntype wide band gap 3. Synthesis, characterization and application of sno 2. Nanoparticles are currently made out of a very wide variety of materials, the most common of the new generation of nanoparticles being ceramics, which are best split into metal oxide ceramics, such as titanium, zinc, aluminum and iron oxides, to name a prominent few, and silicate nanoparticles silicates, or silicon oxides, are also. Largescale electrochemical synthesis of sno nanoparticles. The phase and purity of the asprepared sno 2 nanoparticles were determined by xrd. The average particle size 73nm of the sno2 nanoparticles, estimated by spm. Influence of solvent on structural, morphological and optical. Application of sno2 nanoparticles and zeolites in coal mine. Microwaveassisted synthesis and investigation of sno2. Photoluminescence properties of sno2 nanoparticles. Preparation and characterization of sno2 nanoparticles. An overview of preparation and characterization sovan lal pal, utpal jana, p. For the tetragonal phase of sno2, several groups have indicated that the 110 and 001 surfaces have the lowest and the highest surface energies, respectively 10.
The formation of nanoparticles can be attributed to the following mechanism. Using the twodifferent method xrd study showed well crystallized tetragonal sno2 can be obtained and the crystal sizes were 16. Xray diffraction xrd, field emission scanning electron microscopy, and transmission electron microscopy tem were employed to characterize the asprepared product, and optical property was studied by uvvisible diffuse reflectance. It means that sno2 prefer to grow along the 110 direction, forming the sno2 nanostructure. Tin dioxide sno2 nanoparticles have been synthesized in bulk quantity by thermal evaporation of sno powder. The synthesized sno2 nanoparticles were characterized by xray diffraction xrd, fourier transform infrared spectroscopy ftir, scanning electron microscopy sem, transmission electron microscopy tem, to find their structure and crystal size, functional group, particle. The crystallite size of the prepared sno 2 is in the range of 1632 nm, which was calculated according to scherrer equation of d0. Rietveld analysis of xrd measurements and phonon moments are used to deduce the msd and dwf of nano sno2. Scanning electron microscopy sem analysis shows that the size of the synthesized sno2 nanoparticles is relatively homogeneous with diameter of about 10 nm. Sno2 powder particles have been studied intensively as one of the best gas sensing materials because they exhibit very good sensitivity, selectivity and reproducibility due to their nanograined. Sizecontrolled synthesis of sno2 nanoparticles by solgel. Based on the 110 and 101 diffraction peaks, the average size was found to be 15. The results showed promising reversibility, cycle life and high capacity for lithium insertion into the sno2 nanoparticles. This method is capable of high rate of production of 3gmmin.
Conclusions tin oxide sno2 nanostructures are prepared via cost effective and application oriented solgel route. The xray powder diffraction xrd analysis indicates that the nanoparticles are the tetragonal rutile structure of sno2. Investigation of photocatalytic effect of sno2 nanoparticles. The spm image of the surface morphology of the sno2 film gives a good indicator for formation of the sno2 nanoparticles. Synthesis and characterization of sno2 and pani doped sno2. The synthesized nanoparticles have been characterized by xray diffraction xrd and ultravioletvisible spectroscopy uvvis. Abstract in this paper the synthesis of sno2 nanoparticles with average particle size up to about 70 nm using sncl22h2o and nh4oh in. The results show that sno2 nanoparticles become larger with the increasing temperature and the diameter of sno2 nanoparticles is about 23 nm when the temperature is 1050 degrees c. Synthesis and properties of al doped sno nanoparticles. Because of its electrically conducting properties combined with excellent thermal stability and transparency throughout the visible spectrum, tin oxide sno2 is extremely attractive as a transparent conducting material for applications in. Synthesis, structural and optical properties of al doped. Effect of solvent on the synthesis of sno2 nanoparticles. Synthesis and characterization of silver nanoparticles lawrence hall of science, spring 20. Costeffective synthesis method of facile environment friendly sno2.
Manavalan abstract in recent years, there has been an exponential interest in the development of novel drug delivery systems using nanoparticles. In this paper, we firstly outline the syntheses of phasepure sno 2 hierarchical structures with different morphologies such as nanorods, nanosheets, and nanospheres. Jul 27, 2012 this paper demonstrates the synthesis of sno2 nanoparticles using a simple hydrothermal route in the presence of the surfactant hydrazine at 100 c for 12 h. The raman spectra of pure and al doped sno 2 nanoparticles are shown in fig. Synthesis and characterization of sno2 nanoparticles for. Analysis of received sno 2 nanoparticles basic solution. Preparation and characterization of sno nanoparticles by. Preparation and characterization of sno 2 nanoparticles by. Synthesis and characterization of sno2 nanoparticles for pv. There has been increased interest in synthesis and study of nanoparticles due to their smaller size and larger surface area3. It is environmentally hazardous and harmful to human beings and aquatic species. Synthesis by precipitation method and investigation of sno2. These nanoparticles can be used as a source layer for the extraction of electrons in heterojunction organic solar cells.
Plasmon resonance is a collective excitation of the electrons in. Pure tin dioxide sno2 and al doped sno2 nanoparticles are prepared by coprecipitation method. Sno2 nanoparticles were synthesized by microwave assisted hydrothermal method using sncl22h2o as a precursor. Then it was irradiated with house hold microwave oven for 10 min. The emission maximum of 437 nm is lower than the band gap of the sno 2 bulk. The optical bandgap of the sno2 were found to be 3. Pdf sizecontrolled synthesis of sno2 nanoparticles by. Synthesis, structural and optical properties of al doped sno. Theoretical and experimental investigations are made here on the mean square displacement msd and debye waller factor dwf of rutile structure of tin dioxide nanoparticles. Sno2 nanoparticles have been synthesized by high voltage electrolysis. The average particle size determined from spm, is about 73.
Sno2 nanoparticles are synthesized by simple coprecipitation method and structurally characterized by xray diffraction which revealed tetragonal rutile structure. The starting materials are very cheap and the synthesis procedure is simple, and the obtained sno particles are in the nanometer scale and monodispersed with very high surface area. Pdf sizecontrolled synthesis of sno2 nanoparticles by sol. Crystal density, lattice volume and microstrain are found to be nearly constant with annealing temperature, which confirm the formation of monophase sno2. The dielectric properties of the gsno2 nanocomposite were measured in the. Zinc sulphide, nanoparticles, solvothermal method nanotechnology is an emerging area of research in the recent years1,2.
Preparation and characterization of sno2 nanoparticles open. Synthesis, structural and optical characterizations of sno. Influence of solvent on structural, morphological and. According to cooper et al 16, we can define oxygen balance ob of the reaction, as defined in the field of propellants and explosives as follow. Influence of stabilising agents and ph on the size of sno2. The oxygenvacanciesrelated photoluminescence of pure, cerium, and manganesedoped sno2 nanoparticles was. Pdf synthesis and characterization of sno2 nanoparticles.
The xray analysis shows that the obtained nanoparticles are sno 2 and its crystallite size was in the rangeof 1021nm and for pani doped sno 2 nanoparticles, the crystallite size was in the. Thermally treated sno2 with an average diameter of 3. The tin oxide nanopowder have been prepared by sol gel chemical method and deposited on porous silicon by dipping coating technique. Effect of hydrolysis rate on the optical properties article pdf available may 2015 with 1,479 reads how we measure reads. Pdf synthesis and characterizations of sno2 nanoparticles. This convenient synthesis strategy can be applied as a. The xray analysis shows that the obtained nanoparticles are sno 2 and its crystallite size was in the rangeof 1021nm and for pani doped sno 2 nanoparticles, the crystallite size was in the range of 1216nm, which was further confirmed by tem. May 10, 2016 tin oxide sno2 nanoparticles have been synthesized by coprecipitation method. Tin oxide sno2 nanoparticles, as one of the most important semiconductor oxides, has been used as photo catalyst for photo degradation of organic compounds. The aqueous solution in which the precipitation reaction for tin dioxide was carried out contained a tiniv chloride precursor, polyethylenimine pei or polyvinylpyrrolidone pvp, and toctylphenoxypolyethoxyethanol triton x100 as a surfactant with a hydrophiliclipophilic balance hbl of. The amorphous product thus obtained could be transformed to a nanocrystalline phase by heating to 200 c. Numerous research activities around nanoparticles have created a plethora of uses for these particles in fields such as bio technology, drug delivery, optics and electronics.
As i ordered tin oxide nanoparticles from nanoshel, they exhibit many properties magnetic, optical, catalytic and electronic properties, etc. Tin dioxide is an ntype semiconductor with a band gap width of 3. Synthesis and characterization of sno2 nanoparticles. Synthesis of silver nanoparticles by chemical reduction. Sno2 nanoparticles have been synthesized using a mechanochemical method using autoclave. Synthesis of sno 2 nanopowders for advanced ceramics and. Sonochemical synthesis of sno2 nanoparticles and their. The structure and crystalline state of the powders were characterized by xray diffraction. Pegassisted synthesis of sno2 nanoparticles sciencedirect. In the present work we have studied the structural, optical and electrical properties of sno2 nanoparticles. Three fundamental raman peaks at 469, 629, and 770 cm1, corresponding to e g, a 1g, and b 2g vibration modes. The e ect of temperature on grain size of sno2 nanoparticles. This method is mainly used in the synthesis of silver nanoparticles. Aug 19, 2009 sno2 nanocrystaline powders with an average diameter of 1260 nm have been successfully synthesized using different surfactants and a surface modifier,ctab, polyethylene glycol peg and citric acid respectively at different ph via hydrothermal method.
Zinc acetate is used as a precursor material in this case. The morphological, compositional and structural properties of sno2 nanoparticle were characterized by xrd, scanning electron microscopy sem, energy dispersive spectroscopy edx, tga thermogravimetric analysis, electrical conductivity techniques. Uvvis transmission spectroscopy studies show that the band gap energy of pure sno2 is 3. Under these conditions, the relative fine nanoparticles morphology was found. Abstract tin oxide nanoparticles about 4 nm in size were successfully synthesized using hydrothermal method. Nanoparticles can offer significant advantages over the. The absorption spectrum of sno2 nanoparticles showed absorption band at about 290 nm and the band gap energy. Tin dioxide nanoparticles were synthesized by sol gel method and calcined at different temperatures in the range 350 750. Synthesis of sub5 nm codoped sno2 nanoparticles and.
Synthesis and gas sensitivity of sno2 nanoparticles. Tin oxide nanoparticles detailed analysis xrd sem tem. Page 2 declaration i tamasa panigrahi hereby declare that, this project report entitled synthesis and characterization of silver nanoparticles using leaf extract of azadirachta indica, submitted by me, under the guidance of dr. Size dependent dielectric properties of co and fe doped. Solvothermal synthesis and characterization of zinc. Nanoparticles of sno produced by sonochemistry as anode. Its outstanding electrical, optical and electrochemical properties of sno 2 enable applications in solar cells, catalytic support materials, transparent electrodes, and solid state chemical sensors. The xrd pattern of sno2 nanoparticles recorded in the region of 2. Farrukh and rohana a, surfactantcontrolled aqueous synthesis of sno2 nanoparticles via the hydrothermal and conventional heating methods, turk j chem. The solution was stirred with a magnetic stirrer for 30 min in a closed threenecked flask. Tin dioxide sno 2 is an important ntype widebandgap semiconductor, and sno 2 based nanostructures are presenting themselves as one of the most important classes due to their various tunable physicochemical properties. It is proved that peg plays the key role in the formation of the sno 2 nanoparticles. Moreover, sno 2 is widely used for the production of transparent conductive layers or in the production of electrodes in lithium.
Composite electrodes comprised by weight of 80% sno, 10% graphite flakes conductive additive, and 10% polymeric binder an optimal composition were. Synthesis of silver nanoparticles by chemical reduction method and their antibacterial activity maribel g. Great efforts have been devoted to synthesize nanoparticles of semiconductors, owing to their fascinating electronic, catalytic and optical properties, which lead to their potential applications as lightemitting diodes, catalysts and solar cells. It has been found that solvents played important role in controlling the crystallite size of sno2 nanoparticles. Composite electrodes comprised by weight of 80% sno, 10% graphite flakes conductive additive, and 10% polymeric binder an optimal composition were tested as anodes for rechargeable li batteries. Tests antimicrobial properties of silver nanoparticles engineering lab. The structural and optical properties of these sno2 particles are investigated using xray powder diffraction, transmission electron microscopy, uv. Nanoparticles of sno were synthesized sonochemically in mildly basic sncl2 solutions.
Zno nanoparticles with particle size less than 50nm are synthesized by simple sol gel method. Metallic nanoparticles can be synthesized through many methods. Tin oxide sno2 is one of the most intriguing materials to be investigated today, this is because tin dioxide is a wellknown ntype semiconductor with a wide band gap of 3. Synthesis and characterization of zno nanoparticles. Nanocrystalline sno2 particles have been synthesized by a simple sol. Synthesis of sno2 nanoparticles by the solgel method from. It shows that a little bit appreciable changes are appeared when compared the pure sno 2 with the al doped sno 2 nanoparticles. Synthesis and characterization of sno2 nano particles for. This material was characterized by using xrd, sem, edax, tga and electrical conductivity.
In summary, we have successfully prepared the sno 2 nanoparticles by the mild pegmediated hydrothermal method. In a typical procedure, 8 g hydrated tin chloride sncl 2 2h 2 o was dissolved in pure ethanol c 2 h 5 oh. The tin dioxide nanoparticles were prepared by the solgel method. Journal on photonics and spintronics vol2 no2 may 20 issn 2324 8572 print 5 h 2 o and n 2 are produced. This article deals with the properties and applications of tin oxide nanoparticles.
Xrd analysis confirmed the formation of single phase of sno2 nanoparticles. Hydrothermal synthesis of sno2 nanoparticles and their gas. Silver nitrate solution and reducing agent are allowed to follow into a blender like device. The company tested the process using titanium oxide and managed to make spheres measuring 1100 nanometers in diameter, as well as a nucleus covered with many. Characterizes silver nanoparticles with a scanning electron microscope provides synthesized nanoparticles students go to chemistry. Catalyst nanoparticles nps play an important role in the remediation of mb dye. This is to certify that the thesis entitled synthesis and characterization of silver nanoparticles using leaf extract of azadirachta indica by tamasa panigrahi 411ls2058, submitted to the national institute of technology, rourkela for the degree of master of science is a record of bonafide research. A hydrothermal method was used to synthesize nanocrystalline sno2 particles with an average particle size of 3. The structural, morphological, optical properties and electrical properties of the prepared sno2nanopowder are studied.
Synthesis of nanoparticles using rf plasma method e. From two different types of method, the crystallite size of sno2 nanoparticles varies mutually solvent and method. Studies on structural and morphological properties are done by xray diffraction, field emission scanning electron microscopy and electron diffraction xray spectroscopy and optical properties by using uvvisible spectroscopy in diffuse reflectance spectroscopy mode. Synthesis and characterization of sno2 nanoparticles uv. Methylene blue mb, a toxic dye, is predominantly used in various industries. Synthesis and characterization of sno2 nanoparticles by. Xray powder diffraction, ellipsometery and scanning electron. The optical properties were studied by measuring the energy band gap and were found 1. The average grain size of the synthesized nanoparticles was found to be 24.
986 1293 517 1271 1027 143 570 253 348 727 1165 245 572 795 1061 1184 1349 1307 934 781 373 989 1000 219 1446 1211 842 461 860 145 287 69 313 1401 757 968